Wave phenomena

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The properties of light we set off to describe - reflection, refraction, diffraction, and interference - can all be explained, both qualitatively and quantitatively, in terms of light viewed as a wave. The success of these descriptions of the properties of light was a triumph of the wave picture, and by the 1850s this model of light was the generally accepted one.

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    The simplest instance of the effect arises in materials with uniaxial anisotropy. That is, the structure of the material is such that it has an axis of symmetry with no equivalent axis in the plane perpendicular to it. (Cubic crystals are thereby ruled out.) This axis is known as the optical axis of the material, and light with linear polarizations parallel and perpendicular to it has unequal indices of refraction, denoted ne and no, respectively, where the suffixes stand for extraordinary and ordinary. The names reflect the fact that, if unpolarized light enters the material at a nonzero acute angle to the optical axis, the component with polarization perpendicular to this axis will be refracted as per the standard law of refraction, while the complementary polarization component will refract at a nonstandard angle determined by the angle of entry and the difference between the indices of refraction,

        

        known as the birefringence magnitude. The light will therefore split into two linearly polarized beams, known as ordinary and extraordinary. Exceptions arise when the light propagates either along or orthogonal to the optical axis. In the first case, both polarizations and rays are ordinary and are not split. In the second case also, there is no splitting of the light into two separate directions, but the ordinary and extraordinary components travel at different speeds, and the effect is used to interconvert between linear and circular or elliptical polarizations.

        Double refraction also occurs in biaxially anisotropic materials, which are also known as trirefringent, but its description is then substantially more complex

    Uniaxial birefringent materials are classified as positively (or negatively) birefringent when, for light (having parallel and perpendicular components) directed to the optic axis, the refractive index of light polarized parallel to the optic axis is greater (or smaller, respectively) than light polarized perpendicularly to the optic axis.[6] In other words, the polarization of the slow (or fast) wave is parallel to the optical axis when the birefringence of the crystal is positive (or negative, respectively).

    Biaxial crystals are defined as positively (or negatively) birefringent when the slow ray (or fast ray, respectively) bisects the acute angle formed by the optical axes.

    In practice, when using an optical compensator that emits red light, a crystal with positive birefringence appears blue when itslong dimension is parallel to the slow axis of the compensator. In contrast, a crystal with negative birefringence appears yellow when its long dimension is parallel to the slow axis of the compensator, and the slow ray of the compensator is oriented perpendicularly to the long axis of the crystal.[7] The reason for these phenomena is that the wavelength of emitted light is shifted higher in positively birefringent crystals, because the slow ray of the crystal is parallel to the slow axis of the compensator,[7] while for negatively birefringent crystals the wavelength of emitted light is shifted lower, because the fast ray of the crystal is parallel to the slow axis of the compensator.[7] The order of colors resulting from the use of compensators in a polarized light system differs from that of a typical spectrum, instead having an order including yellow-orange-red-violet-blue

    10. Kerr’s effect

    The Kerr effect, also called the quadratic electro-optic effect (QEO effect), is a change in the refractive index of a material in response to an applied electric field. The Kerr effect is distinct from the Pockels effect in that the induced index change is directly proportional to the square of the electric field instead of varying linearly with it. All materials show a Kerr effect, but certain liquids display it more strongly than others. The Kerr effect was discovered in 1875 by John Kerr, a Scottish physicist.[1]

    Two special cases of the Kerr effect are normally considered, these being the Kerr electro-optic effect, or DC Kerr effect, and the optical Kerr effect, or AC Kerr effect.

    The Kerr electro-optic effect, or DC Kerr effect, is the special case in which a slowly varying external electric field is applied by, for instance, a voltage on electrodes across the sample material. Under this influence, the sample becomes birefringent, with different indices of refraction for light polarized parallel to or perpendicular to the applied field. The difference in index of refraction, Δn, is given by

        

        where λ is the wavelength of the light, is the Kerr constant, and is the strength of the electric field. The Kerr constant typically ranges from 10-18 to 10-14 m2Vfor crystals and 10-22 to 10-19 m2Vfor liquids.[2] This difference in index of refraction causes the material to act like a waveplate when light is incident on it in a direction perpendicular to the electric field. If the material is placed between two "crossed" (perpendicular) linear polarizers, no light will be transmitted when the electric field is turned off, while nearly all of the light will be transmitted for some optimum value of the electric field. Higher values of the Kerr constant allow complete transmission to be achieved with a smaller applied electric field.

        Some polar liquids, such as nitrotoluene (C7H7NO2) and nitrobenzene (C6H5NO2) exhibit very large Kerr constants. A glass cell filled with one of these liquids is called a Kerr cell. These are frequently used to modulate light, since the Kerr effect responds very quickly to changes in electric field. Light can be modulated with these devices at frequencies as high as 10 GHz. Because the Kerr effect is relatively weak, a typical Kerr cell may require voltages as high as 30 kV to achieve complete transparency. This is in contrast to Pockels cells, which can operate at much lower voltages. Another disadvantage of Kerr cells is that the best available material, nitrobenzene, is poisonous. Some transparent crystals have also been used for Kerr modulation, although they have smaller Kerr constants.

        In media that lack inversion symmetry, the Kerr effect is generally masked by the much stronger Pockels effect. The Kerr effect is still present, however, and in many cases can be detected independently of Pockels effect contributions.

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